@ToastedPine
to answer your question about brown sugar first you need to understand there is no gluten flour. There’s two proteins and flour that are important: gliadin and glutenin.
When gliadin and glutenin bind with water molecules, they will develop opposite characteristics from each other.
Gliadin is about 30% of the protein in flour. Gliadin becomes sticky and stretchy. It provides the extensibility (ability to stretch) to the dough.
Glutenin it’s about 50% of the protein in flour. Glutenin is the opposite in that it’s functional properties are elasticity, meaning it pulls back into its original shape.
Gluten is a combination of gliadin, glutenin, and water molecules.
So gluten provides elasticity and extensibility. Both of these characteristics are about dough strength.
Dough strength is not the same as structure.
Protein is only a small percentage of flour, 8% - 15% depending on the type of flour. The vast majority is starch.
The starch molecule is made up of a couple types of atoms: amylose and amylopectin.
When heated and exposed to water molecules the atoms in the starch molecules break apart and the water molecules slip between the atom pieces.
The starch molecule as a whole begins to swell as more water molecules enter. Eventually the starch molecule will burst, and the amylose and amylopectin will leak out. This is what thickens whatever it is you’re making, whether it’s a cookie, a cake, or added flour to a sauce, or cornstarch to pastry cream. Starch gelatinization happens in all baking or cooking. End it happens with all starch regardless if it’s flour, cornstarch, potato starch, tapioca starch, etc.
In baking, gliadin, glutenin, and water molecules create gluten which provides dough strength.
Leavening causes the dough to rise/expand. That’s where your dough strength is important.
Then starch, water, and heat triggers starch gelatinization that thickens the risen dough and sets the baked good as it cools.
The function of sugar is to sweeten but it is also a tenderizer (weakens gluten) because it draws water away from flour. The more water available to gliadin and glutenin, the stronger the dough. The less water, the weaker the dough.
So now are you beginning to understand why it is the sugar and not the flour that determines the texture of the cookie?
Now there’s different types of sugars create different characteristics in baked goods.
I don’t have time to get into all the details on the sugars. But brown sugar contains molasses. If you’re going to use molasses make sure it is not blackstrap. Blackstrap molasses is from the third boil, so it is very bitter. Truly in the south it’s used for animal feed. My grandmother was a southerner that crap is not eaten in the south by humans. It’s pig feed. Buy a molasses like Grandma‘s Original brand.
Molasses is an invert sugar. Invert sugars are more hygroscopic than granulated sugar.
Other invert sugars are Lyle’s golden syrup which is my preferred invert sugar. It is a British product so a bit difficult to find in the US. Which is odd because the company was is purchased by an American sugar company which is headquartered in Florida. Go figure. Corn syrup is also an invert sugar.
You should limit the amount of invert sugar to no more than 15%. too much invert sugar will cause the cookie to crumble. remember sugar is a tenderizer (it weakens gluten). I’ll explain more about calculating percentages of an ingredient below.
To make your cookie less sweet, but to keep it chewy, use a mix of three sugars: granulated sugar, brown sugar, and invert sugar. But reduce the overall ratio of sugar to flour.
If you are not already doing so, bake by weight. baking by weight allows you to scale all your ingredients against the flour.
The average American style chocolate chip cookie contains 110% sugar to flour ratio. that means there’s 10% more sugar than flour by weight. Personally I find that way too sweet.
Depending on the type of chocolate you use you can drop the ratio as low as 95% to sugar to flour ratio.
When I talk about these ratios I am referring to Baker’s percentages.
Flour is always 100%. All other ingredients are weighed against the flour.
Example of baker’s percentages for a cookie.
- Flour 100%
- Sugars 110%
- Butter 70%
- Eggs 35%
- Salt 2%
- Baking soda 1.4%
- Chocolate chips 125%
A standard batch of cookies is usually about 280 g of flour. Since everything is based on the weight of the flour you multiply everything by that weight: 280.
Sugar is 110% (same as 1.10).
280 x 1.10 = 308
Total sugar would be 308g.
If you want a less sweet cookie. So you experiment by recusing the total sugars. So try a batch at 98%
280 x .98 = 274.4.
Total sugar is 274g.
How you want to divide the sugars up is your choice.
You could do 15% of it invert sugar and divide the remainder equally between brown sugar and invert sugar.
274 x .15 = 41.
So 41 g would be invert sugar. That would leave 206 g. 103 g each of granulated sugar and brown sugar.
you may find that 15% is too much so the next batch you may decide to reduce the invert sugar to 10%.
280 x .10 = 28g. So 28g invert sugar and 126g each of the granulated sugar and brown sugar.
The important thing is baking by weight and baker’s percentages. That’s how you adjust your recipes.
And weigh your eggs. Never bake by number of eggs. You should always know the weight of the egg in your recipe even if it means taking out a little tiny quarter of a teaspoon to get the weight of your egg correct.
video that explain starch gelatinization in bread.
Video that explains starch gelatinization in general